一步法合成(E)-1,3-二取代丙-2-烯-1-酮类化合物

报道了一种温和的,以二氧化锰为氧化剂,通过串联氧化反应-Wittig反应-氧化反应,一步制备(E)-1,3-二取代丙-2-烯-1-酮类化合物的合成方法。使用该方法,我们合成7个具有代表性的化合物。     

灭菌器细小塑件组合注射模设计

针对灭菌器细小塑件的结构与使用特征,确定该模具采用多种塑件混排、侧浇口进料、转浇口镶件、弹簧侧抽、联合脱模机构的总体结构,重点介绍了该模具的结构、工作过程以及结构设计要点。经检验,塑件外观光滑、美观,模具动作灵活、可靠。     

6-DOF主动波浪补偿液压平台的结构优化分析

开展6-DOF船用主动波浪补偿液压平台结构优化设计,旨在提升波浪补偿液压平台承载和空间补偿能力,减小补偿平台体积和质量。依据海浪运行形态给定六自由度船用波浪补偿液压平台所需的补偿参数指标,利用虚拟样机技术,在ADAMS软件仿真环境中建立该平台的参数化模型;以其最大负载为优化目标,对该参数化模型的结构尺寸进行优化,得到该平台结构尺寸的优化结果。结果表明：优化后,六自由度船用波浪补偿液压平台的负载能力较最初增加了约15%,支腿液压缸的行程减小了约13%,平台负载能力提升且结构更加紧凑合理。为检验此次对平台结构尺寸优化的有效性,利用SolidWorks软件建模,并导入ADAMS软件中仿真,检验了模型的补偿能力。     

Pavement properties of asphalt modified with packaging‐waste polyethylene

Recycled packaging‐waste polyethylene (WPE) was used to replace the ordinary polymer modifier in the modification of raw asphalt, and the pavement properties of the modified asphalt were studied. The high‐temperature stability, anti‐cracking properties at low temperature, life span, and stability against water of the asphalt mixture were improved, a finding which is attributed to the properties and characteristics of WPE, the swelling of sheared WPE, and the WPE/asphalt network structure. The use of packaging WPE can improve the pavement properties of asphalt, as well as save resources and reduce white pollution. J. VINYL ADDIT. TECHNOL., 20:31–35, 2014. © 2014 Society of Plastics Engineers     

江西九江地震房屋震害分析

本文根据地震现场考察,介绍了江西九江5.7级地震造成砌体结构和钢筋混凝土框架结构房屋的震害情况,研究了房屋的震害特征,对房屋破坏原因作了初步分析,总结了防御和减轻震害的经验和教训。     

型钢混凝土结构(SRC)设计规程比较

首先对日本及欧美等国外有关型钢混凝土(SRC)结构的设计规程进行了介绍,并简单介绍了我国现有的关于型钢混凝土(SRC)结构的两部规程《钢骨混凝土结构设计规程》(YB 9082-97)及《型钢混凝土组合结构技术规程》(JGJ 138-2001)的编制背景和依据。对两部规程中有关型钢混凝土梁的正截面抗弯、斜截面抗剪承载能力、型钢混凝土(SRC)偏心受压构件、剪力墙和梁柱节点的计算理论和计算方法进行了重点比较分析,并结合型钢混凝土(SRC)梁、型钢混凝土(SRC)偏心受压构件和梁柱节点承载能力的计算实例,对两部规程的应用方法、计算步骤和计算结果做了比较分析,为使用两部型钢混凝土结构设计规程提供参考。     

Adsorption mechanism-based screening of cyclodextrin polymers for adsorption and separation of pesticides from water

A rational screening of cyclodextrin-based polymer (CDP), in terms of the relationship between adsorption potential and adsorbent-adsorbate, was investigated to adsorb and separate pesticides from water. Seven spherical porous CDPs were prepared with onefold or composite cyclodextrin(s) as complex and epichlorohydrin as cross-linking reagent. The adsorption kinetics and isotherms of the polymers toward a mixture of ten distinct pesticides clearly demonstrate that the adsorbents with a homogeneous open network structure can absorb pesticides via multiple adsorption interactions such as CD inclusion, loading into swelling water and physical adsorption on network. The multivariate regression analysis distinguishes the quantitative contributions of polymer properties to its adsorption potential, among which CD content, swelling capacity and pore size appear to be major influencing factors. Consequently, a facile mixture of three CDPs (i.e., β-CDP, RM-CDP and HP-CDP) was screened to obtain above prerequisite properties. The multiplex polymer could superiorly separate the pesticides at environmentally relevant levels from water.     

循环流化床脱硫技术的冷态实验研究

研究循环流化床的冷态动力学特征。实验表明，排渣装置加导流板和反应器底部加文丘里布风装置后，反应器内的回流区消失，流场变得稳定，速度分布比较均匀，反应器内的流化状况得到改善，而且整个系统的阻力没有明显增加。实验结果为热态实验提供了重要的参考依据。     

钢管混凝土核心柱轴压组合性能分析

对于钢管混凝土核心柱,核心钢管混凝土和外围普通混凝土的受压性能存在明显差异,本文分析了外围混凝土体积配箍率等因素对柱协同工作的影响,推导出了临界状态时外围混凝土柱的配箍率,并与试验值进行对比,吻合良好。     

宁淮高速公路老山隧道围岩分类方法探讨

确定隧道围岩质量是隧道设计、施工和管理过程中首先应考虑的问题。根据围岩的质量差异,采取相应的支护措施和施工工艺,同时,由于围岩质量的差异,对工程投资和成本产生很大的影响。目前,隧道围岩分类主要是依靠定性和经验的方法,采用模糊数学的方法从定量的角度对隧道围岩分级。